How do you get the LCS 2014 - Roccat?
It was sold in the League of Legends store. Riot's description in the client reads: “This icon was released in the store for purchase during the 2014 esports season.”
Is the LCS 2014 - Roccat still available?
Probably not. Riot tied the LCS 2014 - Roccat to 2014 (store purchase), and it does not normally bring back past event rewards or bundles.
