How do you get the Season 2020 - Flex Master Icon?
It was a ranked reward. Riot's description in the client reads: “This icon was earned by finishing Master in Flex Queue in Season 2020”
Is the Season 2020 - Flex Master Icon still available?
No. The Season 2020 - Flex Master Icon was a ranked reward: to get it you had to reach Master in Flex during Season 10 (2020). Riot does not give out past ranked rewards again, so it cannot be earned anymore.
Season 2020 - Flex Master Icon is one of the rarest LoL summoner icons.
