How do you get the Season 2020 - Solo/Duo Iron Icon?
It was a ranked reward. Riot's description in the client reads: “This icon was earned by finishing Iron in Solo/Duo Queue in Season 2020”
Is the Season 2020 - Solo/Duo Iron Icon still available?
No. The Season 2020 - Solo/Duo Iron Icon was a ranked reward: to get it you had to reach Iron in Solo/Duo during Season 10 (2020). Riot does not give out past ranked rewards again, so it cannot be earned anymore.
